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Radioactivity

Radioactivity

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Board Coverage AQA Paper 2 | Edexcel CP3 | OCR (A) Paper 2 | CIE P4

Alpha Decay

Explore the simulation above to develop intuition for this topic.

Definition. Radioactivity is the spontaneous emission of radiation from unstable atomic nuclei.

1. Nuclear Structure

The atom consists of a nucleus containing protons and neutrons (collectively called nucleons), surrounded by electrons.

PropertyProtonNeutronElectron
Charge+e+e00e-e
Mass (u)1.007281.007281.008671.008670.000550.00055
LocationNucleusNucleusElectron shells

Notation. A nuclide is written as \prescriptAZX\prescript{A}{}{Z}\mathrm{X} where AA is the mass number (nucleon number) and ZZ is the atomic number (proton number). The neutron number is N=AZN = A - Z.

Isotopes are atoms of the same element (same ZZ) with different mass numbers (different NN).

2. Types of Radioactive Decay

Alpha Decay (α\alpha)

Definition. An alpha particle (α\alpha) is a helium nucleus (\prescript42He\prescript{4}{}{2}\mathrm{He}), emitted during alpha decay.

\prescriptAZX\prescriptA4Z2Y+\prescript42α\prescript{A}{}{Z}\mathrm{X} \to \prescript{A-4}{}{Z-2}\mathrm{Y} + \prescript{4}{}{2}\alpha

Conservation checks:

  • Mass number: A=(A4)+4A = (A-4) + 4 \checkmark
  • Atomic number: Z=(Z2)+2Z = (Z-2) + 2 \checkmark

Alpha particles are highly ionising but poorly penetrating (stopped by paper or a few cm of air).

Beta Decay (β\beta^-)

Definition. A beta particle (β\beta^-) is an electron emitted when a neutron converts to a proton in beta-minus decay.

A neutron converts to a proton, emitting an electron and an antineutrino:

\prescriptAZX\prescriptAZ+1Y+\prescript01β+νˉe\prescript{A}{}{Z}\mathrm{X} \to \prescript{A}{}{Z+1}\mathrm{Y} + \prescript{0}{}{-1}\beta^- + \bar{\nu}_e

Conservation checks:

  • Mass number: A=A+0A = A + 0 \checkmark
  • Atomic number: Z=(Z+1)+(1)Z = (Z+1) + (-1) \checkmark
  • Charge: 0=(+1)+(1)+00 = (+1) + (-1) + 0 \checkmark

The antineutrino was postulated by Fermi (1934) to conserve energy and momentum — the observed electron energy spectrum is continuous, implying a third particle carries away the remaining energy.

Penetration: Beta particles are moderately ionising, stopped by a few mm of aluminium.

Beta-Plus Decay (β+\beta^+)

Definition. A beta-plus particle (β+\beta^+) is a positron emitted when a proton converts to a neutron in beta-plus decay.

A proton converts to a neutron, emitting a positron and a neutrino:

\prescriptAZX\prescriptAZ1Y+\prescript0+1β++νe\prescript{A}{}{Z}\mathrm{X} \to \prescript{A}{}{Z-1}\mathrm{Y} + \prescript{0}{}{+1}\beta^+ + \nu_e

This only occurs in proton-rich nuclei.

Gamma Decay (γ\gamma)

Definition. A gamma ray (γ\gamma) is high-energy electromagnetic radiation emitted during nuclear transitions.

After alpha or beta decay, the daughter nucleus is often in an excited state. It de-excites by emitting a gamma ray (high-energy photon):

\prescriptAZX\prescriptAZX+γ\prescript{A}{}{Z}\mathrm{X}^* \to \prescript{A}{}{Z}\mathrm{X} + \gamma

No change in AA or ZZ. Gamma rays are weakly ionising but highly penetrating (stopped by thick lead or concrete).

warning

Common Pitfall In β\beta^- decay, the mass number AA does not change — only the atomic number changes. A neutron becomes a proton, so the total nucleon count is unchanged.

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Board Coverage AQA Paper 2 | Edexcel CP3 | OCR (A) Paper 2 | CIE P4

RequirementAQAEdexcelOCR (A)CIE
Alpha decay equationsYesYesYesYes
β\beta^- decay equationsYesYesYesYes
β+\beta^+ decay equationsRequiredRequiredNot in coreYes
Neutrino / antineutrinoQualitativeQualitativeQualitativeDetailed
Spontaneous vs random natureRequiredRequiredRequiredRequired

3. Exponential Decay Law

Derivation of N=N0eλtN = N_0 e^{-\lambda t}

Definition. The decay constant λ\lambda is the probability per unit time of a nucleus decaying.

λ=LBln2RB◆◆LBt1/2RB\boxed{\lambda = \frac◆LB◆\ln 2◆RB◆◆LB◆t_{1/2}◆RB◆}

The probability that any single nucleus decays in a small time interval dtdt is λdt\lambda\,dt.

If there are NN nuclei, the number decaying in dtdt is:

dN=λNdtdN = -\lambda N\,dt

(The minus sign indicates NN decreases.)

dNdt=λN\frac{dN}{dt} = -\lambda N

Separating variables and integrating:

N0NdNN=0tλdt\int_{N_0}^{N}\frac{dN}{N} = -\int_0^t\lambda\,dt

lnNlnN0=λt\ln N - \ln N_0 = -\lambda t

ln(NN0)=λt\ln\left(\frac{N}{N_0}\right) = -\lambda t

N=N0eλt\boxed{N = N_0 e^{-\lambda t}}

Activity

Definition. Activity AA is the rate of decay of a radioactive sample: A=λN=dNdtA = \lambda N = -\frac{dN}{dt}.

A=λN=dNdt\boxed{A = \lambda N = -\frac{dN}{dt}}

Expanding using the exponential decay law:

A=λN0eλt=A0eλtA = \lambda N_0 e^{-\lambda t} = A_0 e^{-\lambda t}

Definition. The becquerel is the SI unit of activity; 1 Bq = 1 decay per second.

1Bq=1decays1\boxed{1\,\mathrm{Bq} = 1\,\mathrm{decay s}^{-1}}

Half-Life

Definition. The half-life t1/2t_{1/2} is the time taken for half of the radioactive nuclei in a sample to decay.

N(t)=N02t/t1/2\boxed{N(t) = N_0 \cdot 2^{-t/t_{1/2}}}

Setting N=N0/2N = N_0/2:

N02=N0eλt1/2\frac{N_0}{2} = N_0 e^{-\lambda t_{1/2}}

12=eλt1/2\frac{1}{2} = e^{-\lambda t_{1/2}}

ln2=λt1/2\ln 2 = \lambda t_{1/2}

t1/2=LBln2RB◆◆LBλRB\boxed{t_{1/2} = \frac◆LB◆\ln 2◆RB◆◆LB◆\lambda◆RB◆}

Intuition. After one half-life, half remain. After two, a quarter. After nn half-lives, N=N0/2nN = N_0/2^n. The decay is exponential — the activity is always proportional to the number of remaining nuclei, so it decreases exponentially.

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tip straight line with gradient =λ=-\lambda. The half-life can be found by finding the time for the activity to halve at any point on the curve.

Radiation Detection

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Geiger-Muller Tube

The Geiger-Muller (GM) tube is the most common radiation detector. It consists of a thin-walled metal tube filled with an inert gas (typically argon) at low pressure, with a central anode wire held at high positive potential.

When ionising radiation enters through the thin mica window, it ionises gas atoms. The freed electrons are accelerated towards the anode, gaining enough energy to ionise further atoms in an avalanche process. Each avalanche produces a current pulse, which is counted electronically.

  • The GM tube has a dead time of approximately 100μs100\,\mu\mathrm{s} after each count, during which it cannot detect further radiation. At very high activities this leads to count rates lower than the true activity.
  • Background radiation (typically 20-40 counts per minute in the UK) must be subtracted from all measurements.

Definition. Background radiation is the ionising radiation present in the environment from natural and artificial sources.

Sources of background radiation include:

  • Radon gas (from uranium decay in rocks) — the largest single source in the UK, contributing approximately 50% of background dose.
  • Cosmic rays — high-energy particles from space, increasing with altitude.
  • Medical sources — X-rays and nuclear medicine procedures.
  • Ground and building materials — naturally occurring radioactive isotopes such as 40K{}^{40}\mathrm{K} and 238U{}^{238}\mathrm{U}.
  • Food and drink — trace amounts of 40K{}^{40}\mathrm{K} and 14C{}^{14}\mathrm{C}.
warning

warning because: (1) the detector only intercepts a fraction of emitted radiation (solid angle factor), and (2) not all radiation that enters the tube produces a count (detection efficiency is typically 1-2% for gamma rays). Never assume count rate equals activity.

Scintillation Detector

A scintillation detector uses a crystal (e.g. sodium iodide) that emits flashes of light when radiation passes through it. The light pulses are converted to electrical signals by a photomultiplier tube. Scintillation detectors are more sensitive than GM tubes and can distinguish between different types of radiation by the intensity of the light pulse (pulse-height analysis), making them useful for identifying specific isotopes.

Half-Life Measurement Techniques

Graphical Method

To determine half-life experimentally:

  1. Measure the corrected count rate (subtracting background) at regular time intervals.
  2. Plot a graph of corrected count rate (or activity) against time.
  3. Find the time for the count rate to halve — this is t1/2t_{1/2}.
  4. Alternatively, plot lnA\ln A vs tt; the gradient equals λ-\lambda.

The logarithmic method is more accurate because it uses all data points, not just a single halving:

lnA=lnA0λt\ln A = \ln A_0 - \lambda t

The gradient of the straight line gives λ-\lambda, and then t1/2=ln2/λt_{1/2} = \ln 2 / \lambda.

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Exam Technique When describing an experimental method for determining half-life, always mention: (1) measuring background count rate first, (2) subtracting it from all readings, (3) taking readings at regular intervals, and (4) using a log-linear graph for greater accuracy.

Practical Considerations

  • For short half-lives (seconds to minutes), readings can be taken in real time with a GM tube and data logger.
  • For long half-lives (years to millennia), direct measurement is impractical. Instead, measure a known mass of the isotope and use A=λNA = \lambda N where NN is calculated from the mass and Avogadro's number.
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Board Coverage AQA requires the graphical method; Edexcel and OCR (A) additionally require discussion of uncertainties and the effect of dead time on accuracy; CIE requires the logarithmic method.

Problem Set

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Problem 1 Radium-226 undergoes alpha decay. Write the nuclear equation and identify the daughter nucleus.

Answer. \prescript22688Ra\prescript22286Rn+\prescript42α\prescript{226}{}{88}\mathrm{Ra} \to \prescript{222}{}{86}\mathrm{Rn} + \prescript{4}{}{2}\alpha.

Daughter nucleus: Radon-222.

If you get this wrong, revise: Alpha Decay

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Problem 2 Carbon-14 undergoes beta-minus decay. Write the nuclear equation.

Answer. \prescript146C\prescript147N+\prescript01β+νˉe\prescript{14}{}{6}\mathrm{C} \to \prescript{14}{}{7}\mathrm{N} + \prescript{0}{}{-1}\beta^- + \bar{\nu}_e.

If you get this wrong, revise: Beta Decay (β\beta^-)

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Problem 3 A radioactive sample has a half-life of 5.0 hours. If the initial activity is 800 Bq, what is the activity after 20 hours?

Answer. Number of half-lives: n=20/5=4n = 20/5 = 4. A=800/24=800/16=50A = 800/2^4 = 800/16 = 50 Bq.

If you get this wrong, revise: Half-Life

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Problem 4 A sample contains 4.0×10124.0 \times 10^{12} nuclei of a radioactive isotope with decay constant 1.2×1071.2 \times 10^{-7} s1^{-1}. Calculate the initial activity and the number of nuclei remaining after 2.0 hours.

Answer. A0=λN0=1.2×107×4.0×1012=4.8×105A_0 = \lambda N_0 = 1.2 \times 10^{-7} \times 4.0 \times 10^{12} = 4.8 \times 10^5 Bq.

t=7200t = 7200 s. N=N0eλt=4.0×1012×e1.2×107×7200=4.0×1012×e0.864=4.0×1012×0.421=1.68×1012N = N_0 e^{-\lambda t} = 4.0 \times 10^{12} \times e^{-1.2 \times 10^{-7} \times 7200} = 4.0 \times 10^{12} \times e^{-0.864} = 4.0 \times 10^{12} \times 0.421 = 1.68 \times 10^{12}.

If you get this wrong, revise: Exponential Decay Law

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Problem 5 Derive the relationship t1/2=ln2/λt_{1/2} = \ln 2/\lambda.

Answer. At t=t1/2t = t_{1/2}: N=N0/2N = N_0/2. From N=N0eλtN = N_0 e^{-\lambda t}: 12=eλt1/2\frac{1}{2} = e^{-\lambda t_{1/2}}. Taking natural logs: ln(1/2)=λt1/2\ln(1/2) = -\lambda t_{1/2}. ln2=λt1/2-\ln 2 = -\lambda t_{1/2}. t1/2=ln2/λt_{1/2} = \ln 2/\lambda.

If you get this wrong, revise: Half-Life

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Problem 6 The activity of a sample decreases from 1200 Bq to 150 Bq in 30 minutes. Calculate the half-life.

Answer. 150/1200=1/8=1/23150/1200 = 1/8 = 1/2^3. So 3 half-lives have elapsed. t1/2=30/3=10t_{1/2} = 30/3 = 10 minutes.

If you get this wrong, revise: Half-Life

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Problem 7 Explain why the antineutrino was proposed in beta decay.

Answer. In beta decay, the emitted electron has a continuous energy spectrum rather than a single energy. This appeared to violate conservation of energy. Pauli proposed (1930) and Fermi formalised (1934) the existence of an unseen particle (the antineutrino) that carries away the remaining energy and momentum. The total energy of electron + antineutrino equals the fixed energy released by the nuclear transition, conserving energy. The antineutrino was experimentally detected in 1956 by Cowan and Reines.

If you get this wrong, revise: Beta Decay (β\beta^-)

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Problem 8 A sample of iodine-131 has a half-life of 8.04 days. How long does it take for the activity to fall to 5% of its initial value?

Answer. 0.05=eλt0.05 = e^{-\lambda t}. ln0.05=λt\ln 0.05 = -\lambda t. λ=ln2/t1/2=0.693/8.04=0.0862\lambda = \ln 2/t_{1/2} = 0.693/8.04 = 0.0862 day1^{-1}.

t=ln0.05/λ=3.00/0.0862=34.8t = -\ln 0.05/\lambda = 3.00/0.0862 = 34.8 days.

If you get this wrong, revise: Exponential Decay Law

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Problem 9 Compare and contrast alpha, beta, and gamma radiation in terms of: (a) nature, (b) ionising power, (c) penetrating power, (d) deflection in electric and magnetic fields.

Answer. (a) α\alpha: helium nucleus (2p, 2n). β\beta: electron/positron. γ\gamma: electromagnetic photon.

(b) Ionising power: α>β>γ\alpha > \beta > \gamma (alpha has the largest charge and slowest speed, maximising interaction).

(c) Penetrating power: γ>β>α\gamma > \beta > \alpha (alpha stopped by paper, beta by aluminium, gamma by thick lead).

(d) Deflection: α\alpha and β\beta are deflected (opposite directions since opposite charges). α\alpha deflection is less (larger mass). γ\gamma is undeflected (no charge).

If you get this wrong, revise: Types of Radioactive Decay

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Problem 10 A radioactive isotope X with half-life 12 hours decays to a stable daughter Y. A sample initially contains 1000 atoms of X. How many atoms of Y are present after 36 hours?

Answer. After 36 hours: n=36/12=3n = 36/12 = 3 half-lives. NX=1000/23=125N_X = 1000/2^3 = 125. Atoms of Y = 1000125=8751000 - 125 = 875.

If you get this wrong, revise: Exponential Decay Law

4. Decay Chains

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Board Coverage AQA Paper 2 | Edexcel CP3 | OCR (A) Paper 2 | CIE P4

Definition. A decay chain (or radioactive series) is a sequence of radioactive decays where each daughter nuclide is itself radioactive, continuing until a stable nuclide is reached.

The Uranium-238 Decay Series

The most important natural decay chain begins with uranium-238 and ends at stable lead-206 after 14 decays (8 alpha and 6 beta-minus):

\prescript23892Uα\prescript23490Thβ\prescript23491Paβ\prescript23492Uα\prescript20682Pb\prescript{238}{}{92}\mathrm{U} \xrightarrow{\alpha} \prescript{234}{}{90}\mathrm{Th} \xrightarrow{\beta^-} \prescript{234}{}{91}\mathrm{Pa} \xrightarrow{\beta^-} \prescript{234}{}{92}\mathrm{U} \xrightarrow{\alpha} \cdots \to \prescript{206}{}{82}\mathrm{Pb}

Verification of net change: 8 alpha decays reduce AA by 8×4=328 \times 4 = 32 and ZZ by 8×2=168 \times 2 = 16. 6 beta-minus decays increase ZZ by 6×1=66 \times 1 = 6 and leave AA unchanged. Net: AA decreases by 32 (238206=32238 - 206 = 32 \checkmark) and ZZ decreases by 10 (9282=1092 - 82 = 10 \checkmark).

Other natural decay chains include:

  • Thorium-232 series \to 208Pb{}^{208}\mathrm{Pb} (6 alpha, 4 beta-minus)
  • Uranium-235 series \to 207Pb{}^{207}\mathrm{Pb} (7 alpha, 4 beta-minus)

Secular Equilibrium

When a long-lived parent nuclide (very large t1/2t_{1/2}) decays through a chain of shorter-lived daughters, a state of secular equilibrium is established after several daughter half-lives. In equilibrium:

λ1N1=λ2N2=λ3N3=\boxed{\lambda_1 N_1 = \lambda_2 N_2 = \lambda_3 N_3 = \cdots}

Each daughter has the same activity as the parent. This has practical importance in radiological protection: the activity of radon-222 (a daughter of 238U{}^{238}\mathrm{U}) in buildings is sustained by the essentially constant uranium in the ground beneath.

warning

warning only when the parent is much longer-lived than all daughters. If a short-lived daughter precedes a long-lived daughter, the long-lived daughter accumulates and can become the dominant radiological hazard.

5. Applications of Radioactivity

Carbon-14 Dating

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Living organisms continuously exchange carbon with the atmosphere, maintaining a constant ratio of 14C{}^{14}\mathrm{C} to 12C{}^{12}\mathrm{C}. Cosmic rays produce neutrons in the upper atmosphere, which react with nitrogen-14:

14N+1n14C+1H{}^{14}\mathrm{N} + {}^{1}\mathrm{n} \to {}^{14}\mathrm{C} + {}^{1}\mathrm{H}

When an organism dies, this exchange stops and the 14C{}^{14}\mathrm{C} decays with a half-life of 5730 years. The age of a sample is found from:

t=LB1RB◆◆LBλRBln(A0A)=LBt1/2RB◆◆LBln2RBln(N0N)t = \frac◆LB◆1◆RB◆◆LB◆\lambda◆RB◆\ln\left(\frac{A_0}{A}\right) = \frac◆LB◆t_{1/2}◆RB◆◆LB◆\ln 2◆RB◆\ln\left(\frac{N_0}{N}\right)

where N0/NN_0/N is the ratio of current 14C{}^{14}\mathrm{C} content to that of a living sample.

Limitations:

  • Effective range is approximately 50,000 years (beyond this, too few 14C{}^{14}\mathrm{C} atoms remain for accurate measurement).
  • Assumes the atmospheric 14C{}^{14}\mathrm{C}/12C{}^{12}\mathrm{C} ratio has been constant. Variations are corrected using calibration curves from tree-ring dating (dendrochronology).
  • Contamination by modern carbon makes samples appear younger; contamination by old carbon makes them appear older.

Nuclear Medicine

Radioactive isotopes are used both diagnostically and therapeutically:

IsotopeHalf-lifeUseReason
99mTc{}^{99m}\mathrm{Tc}6.0 hoursDiagnostic imaging (gamma camera)Emits gamma rays; short half-life limits patient dose
131I{}^{131}\mathrm{I}8.04 daysTreatment of thyroid cancerBeta radiation destroys thyroid tissue; iodine selectively absorbed by thyroid
60Co{}^{60}\mathrm{Co}5.27 yearsRadiotherapy (external beam)High-energy gamma rays for tumour destruction
18F{}^{18}\mathrm{F}110 minutesPET scansPositron emission enables precise 3D imaging

Definition. The effective half-life of a radioactive substance in the body is the time for its activity to fall to half its initial value, combining both physical decay and biological clearance:

LB1RB◆◆LBteffRB=LB1RB◆◆LBtphysicalRB+LB1RB◆◆LBtbiologicalRB\frac◆LB◆1◆RB◆◆LB◆t_{\mathrm{eff}}◆RB◆ = \frac◆LB◆1◆RB◆◆LB◆t_{\mathrm{physical}}◆RB◆ + \frac◆LB◆1◆RB◆◆LB◆t_{\mathrm{biological}}◆RB◆

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Board Coverage The effective half-life is required by Edexcel and OCR (A) but is not explicitly tested by AQA or CIE at A Level.

6. Case Studies

Chernobyl (1986)

The Chernobyl disaster released approximately 5.2×10185.2 \times 10^{18} Bq of radioactive material into the atmosphere. The most significant isotopes released were:

  • Iodine-131 (t1/2=8.04t_{1/2} = 8.04 days): Caused thyroid cancer, particularly in children who drank milk from cows that had grazed on contaminated grass. The short half-life meant the acute danger passed within months.
  • Caesium-137 (t1/2=30.2t_{1/2} = 30.2 years): More persistent contaminant. Caesium behaves chemically like potassium and was taken up by plants and animals, entering the food chain. The 30 km exclusion zone around the reactor remains in place partly because of 137Cs{}^{137}\mathrm{Cs} contamination.

The different half-lives illustrate a key principle: short-lived isotopes produce intense but brief radiation hazards, while long-lived isotopes create lower but persistent contamination.

Fukushima Daiichi (2011)

The Fukushima disaster, triggered by a tsunami following the Tohoku earthquake, released significant quantities of radioactive isotopes including 131I{}^{131}\mathrm{I}, 134Cs{}^{134}\mathrm{Cs} (t1/2=2.06t_{1/2} = 2.06 years), and 137Cs{}^{137}\mathrm{Cs}.

Key differences from Chernobyl:

  • Most radioactive material was released into the Pacific Ocean rather than the atmosphere, leading to rapid dilution of water-soluble isotopes.
  • 134Cs{}^{134}\mathrm{Cs} has a short half-life (2.06 years) and decayed rapidly; 137Cs{}^{137}\mathrm{Cs} remains the primary long-term concern.
  • The disaster highlighted the importance of cooling systems for spent fuel and the vulnerability of nuclear plants to extreme natural events.

Both disasters demonstrate that understanding half-lives is critical for predicting contamination timelines and informing public health responses.

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Exam Application When asked to evaluate the risks from a nuclear incident, consider: (1) which isotopes were released, (2) their half-lives, (3) how they enter the body (inhalation, ingestion, external exposure), and (4) the type of radiation emitted (alpha is most dangerous internally, gamma externally).

Additional Problems

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Problem 11 A sample of ancient wood has a 14C{}^{14}\mathrm{C} activity of 1.5 Bq per gram. A living sample of the same type of wood has an activity of 12.5 Bq per gram. Calculate the age of the ancient wood. (t1/2t_{1/2} of 14C=5730{}^{14}\mathrm{C} = 5730 years.)

Answer. A/A0=1.5/12.5=0.12A/A_0 = 1.5/12.5 = 0.12. ln0.12=λt\ln 0.12 = -\lambda t. λ=ln2/5730=1.209×104\lambda = \ln 2/5730 = 1.209 \times 10^{-4} year1^{-1}. t=ln0.12/(1.209×104)=2.12/(1.209×104)=17,500t = -\ln 0.12/(1.209 \times 10^{-4}) = 2.12/(1.209 \times 10^{-4}) = 17,500 years (2 s.f.).

If you get this wrong, revise: Carbon-14 Dating

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Problem 12 In the uranium-238 decay series, verify that 8 alpha decays and 6 beta-minus decays are consistent with the transformation from 238U{}^{238}\mathrm{U} to 206Pb{}^{206}\mathrm{Pb}.

Answer. After 8 alpha decays: A=2388×4=206A = 238 - 8 \times 4 = 206, Z=928×2=76Z = 92 - 8 \times 2 = 76. After 6 beta-minus decays: AA unchanged, Z=76+6=82Z = 76 + 6 = 82. Final nuclide: A=206A = 206, Z=82Z = 82, which is 206Pb{}^{206}\mathrm{Pb} \checkmark.

If you get this wrong, revise: The Uranium-238 Decay Series

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Problem 13 A GM tube records a count rate of 340 counts per minute from a radioactive source. The background count rate is 25 counts per minute. After 2.5 hours, the count rate (including background) has fallen to 105 counts per minute. Calculate the half-life of the source.

Answer. Corrected initial count rate: 34025=315340 - 25 = 315 cpm. Corrected final count rate: 10525=80105 - 25 = 80 cpm. 80/315=0.25480/315 = 0.254. ln0.254=λ×150\ln 0.254 = -\lambda \times 150 min (2.5 hours). 1.37=150λ-1.37 = -150\lambda. λ=0.00913\lambda = 0.00913 min1^{-1}. t1/2=ln2/0.00913=75.9t_{1/2} = \ln 2/0.00913 = 75.9 minutes.

If you get this wrong, revise: Half-Life Measurement Techniques

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Problem 14 A patient is administered 99mTc{}^{99m}\mathrm{Tc} with a physical half-life of 6.0 hours for a diagnostic scan. The biological half-life of 99mTc{}^{99m}\mathrm{Tc} in the body is 4.8 hours. Calculate the effective half-life and the fraction of the initial activity remaining after 12 hours.

Answer. 1/teff=1/6.0+1/4.8=0.167+0.208=0.3751/t_{\mathrm{eff}} = 1/6.0 + 1/4.8 = 0.167 + 0.208 = 0.375 hour1^{-1}. teff=1/0.375=2.67t_{\mathrm{eff}} = 1/0.375 = 2.67 hours.

After 12 hours: n=12/2.67=4.49n = 12/2.67 = 4.49 effective half-lives. Fraction remaining =1/24.49=1/22.4=0.0446= 1/2^{4.49} = 1/22.4 = 0.0446, i.e. 4.5%.

If you get this wrong, revise: Nuclear Medicine

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Problem 15 Explain why a sample of radon-222 collected from the soil beneath a building continues to produce a detectable activity even after the original radon-222 has been removed, referring to the concept of secular equilibrium.

Answer. Radon-222 is part of the 238U{}^{238}\mathrm{U} decay chain. Its parent, radium-226, has a half-life of 1600 years — much longer than radon-222's half-life of 3.82 days. In secular equilibrium, radon-222 is produced by radium-226 at the same rate it decays, so its activity remains constant. Removing the radon-222 temporarily reduces the activity, but new radon-222 atoms are continuously produced by the long-lived parent, causing the radon activity to rebuild towards its equilibrium value over several radon half-lives (approximately 20-40 days).

If you get this wrong, revise: Secular Equilibrium

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Diagnostic Test Ready to test your understanding of Radioactivity? The diagnostic test contains the hardest questions within the A-Level specification for this topic, each with a full worked solution.

Unit tests probe edge cases and common misconceptions. Integration tests combine Radioactivity with other physics topics to test synthesis under exam conditions.

See Diagnostic Guide for instructions on self-marking and building a personal test matrix.

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Common Pitfalls

  • Confusing alpha, beta, and gamma radiation properties: Alpha particles are helium nuclei (2 protons, 2 neutrons) -- they are heavy, positively charged, and stopped by paper. Beta particles are fast electrons -- they are light, negatively charged, and stopped by aluminium. Gamma rays are electromagnetic waves -- they have no charge or mass and require thick lead or concrete to stop.

  • Not balancing nuclear equations correctly: In a nuclear equation, both atomic number (proton number) AND mass number must be conserved on both sides. When writing beta decay, remember: a neutron becomes a proton PLUS an electron (and an antineutrino). The mass number stays the same but the atomic number increases by 1.

  • Assuming half-life means half the substance is gone: After one half-life, half of the ORIGINAL atoms have decayed and half remain. After two half-lives, one QUARTER of the original remains (not zero). The substance never fully decays -- it approaches zero asymptotically. The activity also halves with each half-life.

  • Confusing activity with count rate: Activity is the total number of decays per second in the sample (Bq). Count rate is what a detector actually measures, which is always LESS than activity because the detector only captures a fraction of the emissions and background radiation adds to the reading.